Since Rick has thrown down the gauntlet on this I thought we could make it into its own thread. As I get older and more geezer like I realize the truth of the statement "the devil is in the details" So I propose that we start talking about such a project and break it down into its various sub projects. I will put an outline together with some points about each subject. I hope that list members will jump in and try some of thngs and also share what THEY have learned or already done along these lines because there are several threads on this site on this very subject.I'm very interested in building one of the video arrangements you describe and look forward to your further posts on what, why, where and especially how.
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Rick Martin
If you google the web on the subject of spectrophotometer or spectroradiometer you will encounter descriptions of instruments that are essentially the same as what we are trying to do. Except the dispersing element (prism OR grating and they are both used in "real" instruments) is a removable hand spectroscope that we want to be able to use with our eyes if we want to. Also we are trying to not spend a million dollars on the project.
So the components of a spectroradiometer are:
1) An energy source. For what we are doing a quartz halogen lamp will furnish light from the near UV into the near IR or about 350 nm on the UV end and way past the 1200 nm on the Near IR where any sensor we are likely to come up with will peter out. Real instruments have deuterium discharge lamps for the UV range or xenon arc lamps or tungsten halogen lamps.
For what we want to do the fiber optic lightsource is perfect. It keeps most of the heat away from the gemstone and can be put and will stay where we want it. You do need to know whether the unit you are using has an IR blocking filter in front of the bulb. Most do and I recommend this because without it the fiber optic bundle may cook and the adhesives holding it together may scorch or color. But just like the astronomers who want to see IR if you want to extend your measurements into the Near IR and work with a camera without the IR filter, then your excitation energy source needs to have the near IR content in it. In some fiber optic lightsources the heat filter is removeable on a slider. others need a screwdriver. I would say leave it in place for the most part.
The new generation of LED lightsources is VERY interesting and cool (thermally speaking as well as neato speaking). But they arent what an audio nut would call "flat frequency response" They have a big peak at 480 nm or so. This is actually a bit handy when using the hand spectroscope because it brightens up the blue end of the spectrum where the eye isnt that sensitive.These are available in flashlights now that will blind you if you put three new triple AAA batteries in them and will keep blinding you for days. Similarly the MiniMaglite is well known to gemologists as a light source and there are a wide variety of such flashlights and bulbs . This is one of the easier parts of the project.
There are also microscope illuminators that have bulbs from 10 to 100 watts. Sometimes called Nicholas illuminators They are bright and could be used. But the typical fiber optic unit is 150 watts and has a fiber end of about 1/4 in diameter plus the metal jacket as opposed to a Nicholas illuminator which usually has an output lens of 1/2 or even larger. So the fiber optic can put more light into the stone and a Nicholas will heat the stome up faster even though it may only be 20 watts.
Here is a URL to Ocean Optics website which has a wealth of info on spectroscopy. They also have VERY cool products. You could whip together a spectrophotometric system from their building blocks very easily. And they have it all , lightsources spectros fiber optic cables everything. The spectra you see for the various lightsources match closely what you see in "the standard references".
http://www.oceanoptics.com/products/spectraloutput.asp
2) The next component would be the sample chamber on a real instrument
On our equivalent unit this is something to hold the stone, baffle it from light reflecting off its shiny surface, shade it and the entrance of the spectroscope from raw emitted light, (And your eyes too so you dont get dazzled) The old aluminum GIA spectroscope outfit had an aluminum base
with about a two inch diameter cylinder. On top of the cylinder was an iris diaphragm. You could close the iris just small enough to hold your stone. inside there was a 45 degree mirror and affixed to the plate was an American Optical stereo microscope Nicholas style illuminator. It could be set to shine into the cylinder and illuminate the stone from the bottom or you could swing it up and shine it down onto the stone. There was also an aluminum arm to hold a Beck wavelength spectrosope and a separate little pilot light to light up the spectroscopes scale. ( I think it was a Beck 2522)
This is a great idea only nowadays I would use LEDs for scale illumination.
Everything associated with this part of the project should be painted flat black so as not to reflect light which hasnt been through the gemstone.
Here is a great closeout item at Harbor Freight that you could use to hold the spectroscope camera combo. This is from China. When made in USA or even in Japan these kind of things were $200 now yours for $20. Designed to hold a dial indicator. Usually these things are magnetic but this one has a powerful suction cup to hold it to a flat surface. They have magnetic ones on sale for about $7 but I dont like having such strong magnets around and I dont work on steel surfaces. They have a few other jewelers tools that arent bad buys if you search around their site. They sell both on the internet and at your local store if you have one.
http://www.harborfreight.com/cpi/ctaf/D ... mber=93476
So much for the easiest part.
3)After the light or energy has been made and passed through the sample it needs to be dispersed into its spectral components. This is done by either one or more prisms, or combinations of diffraction gratings and mirrors. Usually the grating or prism is mounted on a table that can be rotated by a stepper motor. There is a slit which is at the entrance to the compartment holding the dispersion element which can be adjusted (often with a stepper motor under computer control.) Our units dont need to be quite so complicated. Our handspectroscopes are either grating units or prism units , maybe with focusable optics and adjustable slits. For this project I think those two features would be advisable. The OPL unit achieves its ease of use by very clever design but it is probably optimised for use at the eye. Having adjustments affords you a bit of flexibility but you have to learn how to use them Its not very difficult.
I like having both diffraction grating and prism spectroscopes. I know I'm an unrepentant instrument nut. If you can find a used R&J Beck instrument on the internet or somewhere , they had a microscope ocular which was the standard 23.2 mm in diameter. There are a very large number of people making gadgets to help amateur and even professional microscope users couple their video , film and digital cameras to microscopes (as well as astro telescopes, undoubtedly even a BIGGER business) So if you get a Beck Spectroscope it is easy to take out the microscope size eyepiece and insert a camera adapter that will drop right in with your camera attached. Some of the Rayner spectroscopes like the one Rebecca has been restoring were made by Beck. They also had one that would drop into the eyepiece hole of a monocular microscope. That could solve a whole set of thes requirements at one fell swoop. The late great Dr. Eduard Gubelin built a combo microscope spectroscope unit dedicated for gemological spectroscopy. Long time ago. If you think about it its perfect. Mirror to shine up though the gem. Table to baffle the glare. Probably an iris to set the gem on. Low power objective lens , probably less than 10x to make the field of view smaller and therefore only pick up specific light. Stick an eyepiece in, focus on the spot you like then pull the eyepiece and replace it with a spectroscope.The idea was not even new to Dr, Gubelin except for the fact that he was a gemologist. Zeiss , Beck and others had these items for chemical microspectroscopy in the very early twentieth centure maybe even late nineteenth. When examples appear on fleabay the prices make me shudder. I just watch and wish.
Here is a hand spectroscope you can buy for $49. I have no financial interest in surplusshed. I don't own one of these but have played with similar units.
http://www.surplusshed.com/pages/item/i1479d.html
Here is a wavelength scale unit. He quotes 5 degrees of dispersion between the C & F Frauenhoefer lines. This unit sells for $92.50 It is probably an India copy of the Jena spectroscope or more likely a Beck model.
http://www.surplusshed.com/pages/item/l3524.html
Here is a student table spectrometer for $125 You can use this with a grating
or a prism or multiple prisms to increase dispersion. You could mount your camera on this easily.
http://www.surplusshed.com/pages/item/i1430d.html
The above table spectrometer not magnificent enough for ya. Try this one for $325. Heavier built , more adjustments. spammer gemology students also know that the spectrometer can be used not only for spectral work but also can be used , if you are a total glutton for the worst sort of punishement, for determining refractive indices. You also might be able to make accessories for this or the above one to determine RI by the Brewster angle method or by reflectometry. If you are a lab rat.
http://www.surplusshed.com/pages/item/i1476d.htm